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  In the case of coffee, the decaffeination processes are performed on unroasted (green) beans, although the method can vary somewhat. It generally starts with the steaming of the beans. They are then rinsed in solvent that contains as much of the chemical composition of coffee as possible without also containing the caffeine in a soluble form.

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Coffee contains over 400 chemicals important to the taste and aroma of the final drink, which means that there is no no physical process or chemical reaction that will remove only caffeine while leaving the other chemicals at their original concentrations. Therefore, only the caffeine in the bean is allowed to escape whereas the rest of the compounds are in equilibrium. the flavor of batches is intermixed since the chemically saturated solution is used repeatedly.

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  Coffee Products - decaffein coffee
Decaffein Decaffeinated - decaf coffee

Caffeine, which is found in coffee and other foods (cocoa , tea) , is that substance that keeps us awake, both when we need it and when we don't want it. Unfortunately, to some people this and other side effects of caffeine are not welcome.
Decaffeination coffee is where the caffeine is removed from the coffee beans and is known in the trade as decaff or decaf.
 

Decaffeination process based on equilibrium principles and solvent /solute properties. As such, neither all of the caffeine is removed from the coffee, nor are all of the flavour compounds returned or left in the coffee. The chemical composition of decaffeinated coffee is altered, and therefore the flavour and aroma are changed.

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When you read "97% Caffeine Free", 97% of that 1% or 2% has been removed. water procesed decaf - in this decaf process , all components soluble in water other than caffeine.

Decaffeinated coffee or "decaf" is coffee that has had most of the caffeine removed. By weight, the amount of caffeine found naturally in coffee is only about 1% for the Arabica and 2% for the Robusta coffee beans.